Pore Structure and Fractal Character of Lacustrine Oil-Bearing Shale from the Dongying Sag, Bohai Bay Basin, China

نویسندگان

چکیده

To better understand the pore structure and fractal character of lacustrine shales their influence on liquid hydrocarbon occurrences, in this study, a total 29 oil-bearing shale samples collected from Shahejie Formation Dongying Sag, Bohai Bay Basin, were investigated based nitrogen adsorption (NGA) analysis combined with TOC, Rock-Eval pyrolysis, X-ray diffraction (XRD), field emission-scanning electron microscopy (FE-SEM) experiments. The relationships among compositions (TOC, minerals, oil content), structures, dimensions discussed. results showed that characteristics differ at relative pressures 0-0.1 0.5-1. Two corresponding D 1 id="M2"> 2 determined by FHH model according to branches. Specifically, id="M3"> varies 2.4292 2.6109 (mean 2.5245), id="M4"> between 2.4680 2.8535 2.6889). specific surface area (SSA) ranges 1.512 m2/g 34.002 m2/g, an average 13.656 volume is 6.0 × 10-3 cm3/g 48.4 24.5 cm3/g), diameter range 4.22 nm 19.57 9.35 nm). Both id="M5"> id="M6"> increase increasing SSA decreasing diameters but have no correlation volume. Moreover, id="M7"> id="M8"> exhibit positive clay minerals negative correlations carbonate (calcite dolomite). relationship ( id="M9"> id="M10"> ) TOC contents expressed as U-shaped curve, characterized minimum id="M11"> values approximately 3% TOC. content controlled structures dimensions, lower SSAs smaller would more free oil. Therefore, window ranging 2% 4% are probably preferred exploration target Formation, Basin. indicate can provide insight into storage capacity shales.

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ژورنال

عنوان ژورنال: Geofluids

سال: 2021

ISSN: ['1468-8115', '1468-8123']

DOI: https://doi.org/10.1155/2021/9945494